| Campeonato Europeo - Femenino | 2022/08/17 11:45 | Jia Nan Yuan v Aikaterini Toliou | L | 4-3 |
| Campeonato Europeo - Femenino | 2022/08/16 08:45 | Aikaterini Toliou v Dzana Biogradlic | W | 3-0 |
| Campeonato Europeo - Femenino | 2022/08/15 15:00 | Aikaterini Toliou v Natalia Partyka | L | 0-3 |
| Campeonato Europeo - Femenino | 2022/08/14 10:20 | Aikaterini Toliou v Mariona Munne | W | 3-0 |
| ETTU Europe Trophy - Femenino | 2022/06/19 09:30 | Aikaterini Toliou v Mitsuki Yoshida | W | 3-2 |
| ETTU Europe Trophy - Femenino | 2022/06/18 11:05 | Aikaterini Toliou v Katarina Strazar | W | 3-0 |
| WTT Contender Zagreb Women Quals | 2022/06/13 13:30 | Swastika Ghosh v Aikaterini Toliou | L | 3-2 |
| Singapur - WTT Grand Smash - Femenino | 2022/03/08 09:00 | Aikaterini Toliou v Sibel Altinkaya | L | 0-3 |
| Campeonato Europeo - Femenino | 2022/08/19 16:20 | Sabine Winter v Giorgia Piccolin | L | 4-0 |
| Campeonato Europeo - Femenino | 2022/08/19 12:15 | Tatiana Kukulkova v Giorgia Piccolin | W | 1-4 |
| Campeonato Europeo - Femenino | 2022/08/18 08:00 | Giorgia Piccolin v Hana Matelova | W | 4-2 |
| Campeonato Europeo - Femenino | 2022/08/17 09:15 | Giorgia Piccolin v Tessy Gonderinger | W | 4-1 |
| WTT Star Contender Budapest Women Quals | 2022/07/11 14:40 | Andreea Dragoman v Giorgia Piccolin | L | 3-0 |
| WTT Contender Zagreb Women Quals | 2022/06/14 12:00 | Giorgia Piccolin v Yu-Jie Huang | L | 1-3 |
| WTT Feeder Westchester - Femenino | 2022/05/14 15:20 | Sakura Mori v Giorgia Piccolin | L | 4-0 |
| WTT Feeder Fremont - Femenino | 2022/05/07 18:20 | Hsing-Yin Liu v Giorgia Piccolin | L | 4-1 |